3,3,4,4-Tetra­fluoro-1-[2-(3,3,4,4-tetra­fluoro­pyrrolidin-1-yl)phen­yl]pyrrolidine

نویسندگان

  • Jin Wang
  • Jun-Wen Zhong
  • Pei-Lian Liu
  • Wan-Wan Cao
  • Zhuo Zeng
چکیده

The asymmetric unit of the title compound, C(14)H(12)F(8)N(2), contains one tetra-fluoro-pyrrolidine system and one half-mol-ecule of benzene; the latter, together with a second heterocyclic unit, are completed by symmetry, with a twofold crystallographic axis crossing through both the middle of the bond between the C atoms bearing the heterocyclic rings and the opposite C-C bonds of the whole benzene mol-ecule. The pyrrolidine ring shows an envelope conformation with the apex at the N atom. The dihedral angle between the least-squares plane of this ring and the benzene ring is 36.9 (5)°. There are intra-molecular C-H⋯N inter-actions generating S(6) ring motifs. In the crystal structure, the mol-ecules are linked by C-H⋯F inter-actions, forming chains parallel to [010].

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011